Abstract
The possibilities of localised analysis, analysis of both conducting and nonconducting samples, absence of sample preparation and operation at atmospheric pressure inherent to the laser ablation (LA) techniques are of great interest for industrial applications, as they have the premises for becoming general, all-round and robust direct solid-sample analytical techniques. A general description of the laser ablation process, under conditions relevant to analysis, is presented, with special importance given to the choice of the laser source, as recently published results show that the black-box approach, that was previously adopted, is insufficient. The use of sources in the UV (excimer lasers or frequency-tripled or quadrupled Nd: YAG lasers) is shown to be essential for reproducibility. To illustrate the possibilities and limitations of laser ablation, three different analytical techniques are discussed, each making use of a particular phase of the laser ablation process: in LA-OES, that is Optical Emission Spectroscopy, the direct emission of the produced plasma is analysed; in LA-LIF, transitions of the cooled atomic vapour are resonantly excited by a dye-laser; in LA-ICP-OES, the laser is only used as a sampling technique, and the analysis is done on the subsequently formed aggregates by vaporising them in a plasma torch. In each case, the set-up is described and the results obtained on the detection limits and the reproducibility are discussed to show the possibilities of the techniques and ways of further improvement.
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References
Brech, F. and Cross L., Optical micro-emission stimulated by a ruby MASER, Appl. Spectroscopy 16, 59 (1962).
Darke S. and Tyson J., Interaction of laser radiation with solid materials and its significance to analytical spectrometry, J. Anal, and Atomic Spectr. 8, 145 (1993).
Moenke-Blankenburg L., Laser micro-analysis, Prog. Analyt. Spectrosc. 9, 335 (1986).
Geertsen C., Briand A., Chartier F., Lacour J.-L., Mauchien P. and Sjöström S., Comparison between infrared and ultraviolet laser ablation at atmospheric pressure — Implications for solid sampling inductively coupled plasma spectrometry, Journal of Analytical and Atomic Spectrometry 9, 17 (1994).
Kawaguchi H., Xu J., Tanaka T. and Mizuike A., Inductively coupled plasma emission spectrometry using direct vaporisation of metal samples with a low-energy laser, Bunseki Kagaku 31, E185 (1982).
Ishida R. and Kubota M, Studies on the spectrochemical analysis of metal samples by means of the laser microprobe (Part 1): Erosion of pure metals by the normal laser radiation, J. Spectrosc. Soc. Jap. 21, 16 (1972).
Iida Y., Effects of atmosphere on laser vaporisation and excitation processes of solid samples, Spectrochim. Ada 45B, 1353 (1990).
Petite G., Agostini P., Guizard S., Martin P. and Trainham R., “Electron emission by laser irradiated surfaces”, in E. Fogarassy and S. Lazare (eds.), Laser Ablation of Electronic Materials, Elsevier, Amsterdam, p. 21 (1992).
Weyl G. M. and Rosen D., Laser induced breakdown in Argon at 0.35 μm: theory and experiments, Phys. Rev. A31, 2300 (1985).
Autin M., Briand A., Mauchien P. and Mermet J.M., Characterisation by emission spectrometry of a laser-produced plasma from a copper target in air at atmospheric pressure, Spectrochim. Acta 48B, 851 (1993).
Girault C., “Etude du transport des espèces dans le panache plasma créé lors de l’interaction entre divers types de lasers (IR, visible, UV) et de matériaux (métaux, polymères, céramiques)”, Doctoral Thesis, Université de Limoges, France (1990).
Zel’dovich Ya. and Raizer Yu., Cascade ionisation of a gas by a light pulse, Sov. Phys. JETP 20, 772 (1965).
von Allmen M., Laser Beam Interaction with Materials, Springer-Verlag, Berlin, p. 54 (1987)
Rosen D.I., Hastings D.E. and Weyl G.M., Coupling of pulsed 0.35 μm laser radiation to titanium alloys, J. Appl. Phys. 53, 5882 (1982).
Hager J.W., Relative elemental responses for laser ablation inductively coupled plasma mass spectrometry, Anal. Chem. 61, 1243 (1989).
Sdorra W., Quentmeier A. and Niemax K., Basic investigations for laser microanalysis: II. Laser induced fluorescence in laser produced plasma plumes, Mikrochim. Ac ta II, 201 (1989).
Lorenzen C.J., Carlhoff C., Hahn U. and Jogwich M, Applications of laser-induced emission spectral analysis for industrial process and quality control, J. Anal. Atomic Spectr. 7, 1029 (1992).
EEC contract MAT1-CT93-0029, “Study of Emission Spectroscopy on Laser-Produced Plasma for Localised Multi-Element Analysis in Solids with Surface Imaging” (1993).
Measures R.M., Drewell N. and Kwong H.S., Atomic lifetime measurements obtained by the use of laser ablation and selective excitation spectroscopy, Phys. Rev. A16, 1093 (1977).
Leis F., Sdorra W., Ko J.B. and Niemax K., Basic investigations of laser microanalysis: I. Optical emission spectrometry of laser produced sample plumes, Mikrochim. Acta II, 185 (1989).
Abercrombie F.N., Silvester M.D. and Murray A.D., “A new multielement technique for the collection and analysis of airborne particulates in air quality surveys”, in R.M. Barnes (ed.), Applications of ICP to Emission Spectrometry, Franklin Institute Press, Philadelphia, p. 121 (1978).
Chartier F., “Etude et caracterisation du couplage ablation laser/plasma HF (ICP): Application à l’analyse par spectrométrie d’émission optique”, Doctoral thesis, Université Claude Bernard — Lyon 1, France (1991).
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Geertsen, C., Mauchien, P. (1995). Optical Spectrometry Coupled with Laser Ablation for Analytical Applications on Solids. In: Misaelides, P. (eds) Application of Particle and Laser Beams in Materials Technology. NATO ASI Series, vol 283. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8459-3_15
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DOI: https://doi.org/10.1007/978-94-015-8459-3_15
Publisher Name: Springer, Dordrecht
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